Fluorine Chemistry Research

The main interest of Alan Brisdon's research group concerns the chemistry of fluorine and its compounds.

Fluorine Chemistry underpins all of our research work

Fluorine is one of the most reactive elements in the periodic table yet some of its compounds are the most stable and least reactive! Others are even more reactive than fluorine itself! It is the ability of fluorine to drastically alter the steric and electronic properties of its compounds that fascinates us.

Compounds of fluorine find applications in almost all areas of modern life. From fluoride in modern toothpaste to the many different fluorinated plastics and materials, including polytetrafluoroethene, PTFE (tradename Teflon) which is the inert plastic used in "non-stick" pans. Very many modern pharmaceutical compounds (anti-cancer, antibiotics, anti-malerial etc) include fluorine, or fluorinated groups. Fluorine is also heavily involved in environmental chemistry, for example the generation of hydrofluorocarbons (HFCs) has resulted in the rapid phaseout of their ozone-depleting cousins, CFCs.

Research Overview
Our research crosses the traditional inorganic and organic borders, some of it is curiousity driven and some has industrially relevance. Our main areas of research include the chemistry of HFCs, fluorophosphines, organofluorine compounds of main-group and transition metal elements applications of fluorinated materials, such as ionic liquids and fluorographene, and spectroscopy.

Publications
We have published in areas ranging from CFC-related compounds, HFCs, organofluorine chemistry, fluorovinyls, fluoroalkynes, N-F compounds, fluorine-containing phosphorus ligands, fluoro-organometallic systems, metal-based catalysis, high-oxidation metal fluorides, coordination chemistry and ionic liquids.

Research Facilities
Details about the School of Chemistry and our laboratory facilities.

Research Tools
Software to calculate 31P NMR chemical shifts, mass spec patterns and elemental analysis figures. Also access our database of fluorine-containing compound information.

The group, past & present
Details of current and former final year project students, MSc, PhD researchers and visiting academics. Also how to join us.

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Fluorine Events
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1071315
54.167.159.180

Tag Cloud
Fluorine Group News
Fluorine and Carbon standing infront of the transition metals

Fluorine in Organometallic Chemistry
As invited authors in the fluorine in organometallic chemistry special issue of the ACS flagship journal Organometallics we report the synthesis of perfluoropropenyl organometallic species and their use in catalysis. more...

Click for other news

Fluorine@Manchester
solid fluornating agents, funfluos

Solid phase fluorinations
Sven Schroeder's group look at fluorination of organic substrates using solid-phase "functional" catalysts

Fluorine in Society
An LCD display

Modern Display Devices
Flat screen TVs & computer LCD displays work efficiently because they contain fluorine-containing compounds.